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Beilstein J. Org. Chem. 2011, 7, 744–758, doi:10.3762/bjoc.7.85
Graphical Abstract
Figure 1: Chiral aryl selenium electrophiles 1–3.
Scheme 1: Plausible mechanism of alkene selenenylation.
Figure 2: Plot of log krel values for PhSeCl addition to alkenes versus their corresponding IEs. Point number...
Figure 3: Plot of log krel values for PhSeCl addition to alkenes versus their corresponding HOMOs, analogous ...
Figure 4: Plot of log krel versus HOMO shows data grouped by branching at α position. Data are from Table 3; point n...
Scheme 2: Major products from reactions of 1 and 2 with representative alkenols.
Figure 5: Structure of intermediate complex 9.
Figure 6: Plot of log krel values for PhSCl addition to alkenes versus their IEs. Data are from Table 6.